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This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License
Article
Three New Hydrogenosuccinate and Succinate AdductsComplexes: Synthesis and SpectroscopicStudy
Author(s)
BoucarDiouf, Waly Diallo, Bocar Traoré, Daouda Ndoye, Cheikh Abdoul Khadir Diop and Mamadou Sidibé
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DOI:10.17265/2162-5298/2024.06.003
Affiliation(s)
Département de ChimieLaboratoire de ChimieMinérale et Analytique, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Dakar5050, Sénégal
ABSTRACT
One new hydrogenosuccinate and two succinate adduct and complex have
beensynthesized and studied by infrared, UV-Visible and NMR (Nuclear Magnetic
ResonanceSpectroscopy) 119Sn spectroscopies.The suggested structure
is discrete, the hydrogenosuccinate behaving as a monodentateligand or only
involved in hydrogen bonding, the environment around themagnesium centre being
triangular (compound 3). The succiate anion is a monochelatingligand (compound
1 and 2). In all the suggested structures, when extra hydrogenbonds are
considered, supramolecular architectures are obtained (compound 2 and 3).
KEYWORDS
Discrete structures, hydrogen bonds, monochelating, monodentate, triangular or trigonal bipyramidal or tetrahedral environments.
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