 |
[email protected] |
 |
3275638434 |
 |
 |
| Paper Publishing WeChat |
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License
Adsorption of Chromium (VI) from Aqueous Solution Using Zeolit/Chitosan Hybrid Composite
Meiling Pang, Naoki Kano and Hiroshi Imaizumi
Full-Text PDF
XML 2182 Views
DOI:10.17265/1934-7375/2015.07.001
This study investigated the adsorption ability of ZCHC (zeolite/chitosan hybrid composite) as adsorbent for chromium (Cr(VI)), ZCHC was prepared with sol-gel method by mixing zeolite and chitosan. Adsorption experiment from aqueous solutions containing known amount of Cr(VI) using zeolite, chitosan and ZCHC was explored to evaluate the efficiency of ZCHC as adsorbent for Cr in a batch system. The amount of Cr(VI) adsorbed at different pH values, initial concentrations, adsorbent dosages, and contact times were determined by ICP-AES (inductively coupled plasma-atomic emission spectrometry) in order to determine the optimum conditions for Cr(VI) adsorption. Furthermore, the adsorption mechanism of Cr(VI) by zeolite, chitosan and ZCHC was investigated by applying Langmuir and Freundlich isotherm equations to the data obtained. In addition, the rates of adsorption were found to conform to pseudo-second order kinetics.
Adsorption, chromium, zeolite, chitosan, hybrid composite, adsorption isotherms, kinetics.
[1] Saether, O. M., Storroe, G., Segar, D., and Krog, R. 1997. “Contamination of Soil and Groundwater at a Former Industrial Site in Trondheim, Norway.” Applied Geochemistry 12: 327-32.
[2]Dahiya, S., Tripathi, R. M., and Hegde, A. G. 2008. “Biosorption of Heavy Metals and Radionuclide from Aqueous Solutions by Pre-treated Arca Shell Biomass.” J. Hazard. Mater. 150: 376-86.
[3] Pillai, S. S., Mullassery, M. D., Fernandez, N. B., Girija, N. Geetha, P., and Koshy, M. 2013. “Biosorption of Cr(VI) from Aqueous Solution by Chemically Modified Potato Starch: Equilibrium and Kinetic Studies.” Ecotoxicology and Environmental Safety 92: 199-205.
[4] Chauhan, D., Jaiswal, M., and Nalini, S. 2012. “Removal of Cadmium and Hexavalent Chromium from Electroplating Wastewater Using Thiocarbamoyl Chitosans.” Carbohydrate Polymers 88: 670-5.
[5] Kousalya, G. N., Gandhi, M. R., and Meenakshi, S. 2010. “Sorption of Chromium (VI) Using Modified Forms of Chitosan Beads.” International Journal of Biological Macromolecules 47: 308-15.
[6] Motomizu, S., Jitmanee, K., and Oshima, M. 2003. “On-Line Collection/Concentration of Trace Metals for Spectroscopic Detection via Use of STSP (Small-Sized Thin Solid Phase) Column Resin Reactors, Application to Speciation of Cr(III) and Cr(VI).” Analytica Chimica Acta 499: 149-55.
[7] Fukushima, M., Nakayasu, K., Tanaka, S., and Nakamura, H. 1997. “Speciation Analysis of Chromium after Reduction of Chromium (VI) by Humic Acid.” Txicological and Environmental Chemistry 62: 207-15.
[8] Donais, M. K., Henry, R., and Rettberg, T. 1999. “Chromium Speciation Using an Automated Liquid Handling System with Inductively Coupled Plasma-Mass Spectrometric Detection.” Talanta 49: 1045-50.
[9] Acosta, R. I., Rodriguez, X., Gutierrez, C., and Guadalupe, M. M. 2004. “Biosorption of Chromium (VI) from Aqueous Solutions onto Fungal Biomass.” Bioinorganic Chemistry and Application 2: 1-7.
[10] Mungasavalli, D. P., Viraraghavan, T., and Jin, Y. C. 2007. “Biosorption of Chromium from Aqueous Solutions by Pretreated Aspergillus Niger: Batch and Column Studies.” Colloids and Surfaces A: Physicochemical and Engineering Aspects 301: 214-23.
[11] Ertugay, N., and Bayhan, Y. K. 2008. “Biosorption of Cr (VI) from Aqueous Solutions by Biomass of Agaricus Bisporus.” Journal of Hazardous Materials 154: 432-9.
[12] Wan Ngah, W. S., Teong, L. C., Toh, R. H., and Hanafiah, M. A. K. M. 2012. “Utilization of Chitosan–zeolite Composite in the Removal of Cu(II) from Aqueous Solution: Adsorption, Desorption and Fixed Bed Column Studies.” Chemical Engineering Journal 209: 46-53.
[13] Xie, J., Li, C., Chi, L., and Wu, D. 2013. “Chitosan Modified Zeolite as a Versatile Adsorbent for the Removal of Different Pollutants from Water.” Fuel 103: 480-5.
[14] Rahmati, M. M., Rabbani, P., Abdolali, A., and Keshtkar, A. R. 2011. “Kinetics and Equilibrium Studies on Biosorption of Cadmium, Lead and Nickel Ions from Aqueous Solutions by Intact and Chemically Modified Brown Algae.” Journal of Hazardous Materials 185: 401-7.
[15] Mohantly, K., Jha, M., Meikap, B. C., and Biswas, M. N. 2006. “Biosorption of Lanthanides Using Three Kinds of Seaweed Biomasses.” Chemical Engineering Journal 117: 71-7.
[16] Kumar, R., Bishnoi, N. R., and Bishnoi, G. K. 2008. “Biosorption of Chromium (VI) from Aqueous Solution and Electroplating Wastewater Using Fungal Biomass.” Chemical Engineering Journal 135: 202-8.
[17] Dahiya, S., Tripathi, R. M., and Hegde, A. G. 2008. “Biosorption of Lead and Copper from Aqueous Solutions by Pre-treated Crab and Arca Shell Biomass.” Bioresource Technology 99: 179-87.
[18] Wan Ngah, W. S., and Fatinathan, S. 2010. “Pb(II) Biosorption Using Chitosan and Chitosan Derivatives Beads: Equilibrium, Ion Exchange and Mechanism Studies.” Journal of Environmental Sciences 22: 338-46.
[19] Gerente, C., Lee, V. C., Cloirec, P. L., and McKay, G. 2007. “Application of Chitosan for the Removal of Metals from Wastewaters by Adsorption—Mechanisms and Models Review.” Critical Reviews in Environmental Science and Technology 37: 41-127.
[20] Wang, G., Liu, J., Wang, X., Xie, Z. Y., and Deng, N. 2009. “Adsorption of Uranium (VI) from Aqueous Solution onto Cross-Linked Chitosan.” Journal of Hazardous Materials 168: 1053-8.
[21] Wan, W. S., Teong, L. C., and Hanafiah, M. A. 2011. “Adsorption of Dyes and Heavy Metal Ions by Chitosan Composites: A Review.” Carbohydrate Polymers 83: 1446-56.
[22] Liu, B., Lv, X., Meng, X., Yu, G., and Wang, D. 2013. “Removal of Pb(II) from Aqueous Solution Using Dithiocarbamate Modified Chitosan Beads with Pb(II) as Imprinted Ions.” Chemical Engineering Journal 220: 412-9.
[23] Xu, D., Tan, X. L., Chen, C. L., and Wang, X. K. 2008. “Adsorption of Pb(II) from Aqueous Solution to MX-80 Bentonite: Effect of pH, Ionic Strength, Foreign Ions and Temperature.” Appl. Clay Sci. 41: 37-46.
[24] Aksu, Z., Acikel, U., Kabasakal, E., and Tezer, S. 2002. “Equilibrium Modelling of Individual and simultaneous Biosorption of Chromium (VI) and Nickel (II) onto Dried Activated Sludge.” Water Research 36: 3063-73.
[25] Salgado-Gómez, N., Macedo-Miranda, M. G., and Olguín, M. T. 2014. “Chromium (VI) Adsorption from Sodium Chromate and Potassium Dichromate Aqueous Systems by Hexadecyltrimethylammonium-modified Zeolite-rich Tuff.” Appl. Clay Sci. 95: 197-204.
[26] Hamadi, N. K., Chen, X. D., Farid, M. M., and Lu, M. Q. 2001. “Adsorption Kinetics for the Removal of Chromium (VI) from Aqueous Solution by Adsorbents Derived from Used Tyres and Sawdust.” Chemical Engineering Journal 84: 95-105.
[27] Duranoglu, D., Trochimczuk, A. W., and Beker, U. 2012. “Kinetics and Thermodynamics of Hexavalent Chromium Adsorption onto Activated Carbon Derived from Acrylonitrile-Divinylbenzene Copolymer.” Chemical Engineering Journal 187: 193-202.