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New Method of Predicting the Thermodynamic Properties of Solutions
Suntsov Yuri Konstantinovich
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DOI:10.17265/1934-7375/2014.03.013
Department of Physical and Analytical Chemistry, Voronezh State University of Engineering Technologies, Voronezh 394000, Russia
Thermodynamic functions solutions of a 25 binary systems formed n-alcohols and esters of aliphatic acids by were calculated using the standards ideal solution and ideal gas. The value change regularity of the thermodynamic functions of solutions depending on their molar mass and concentration of the solutions’ components was determined by the thermodynamic analysis. The method of prediction of the thermodynamic properties of binary solutions was suggested on the basis of the determined regularities. The corresponding equations were obtained.
Vapor-liquid equilibrium, Helmholtz energy, enthalpy, entropy of solutions, equation of state.